The acid/base-catalysed Kemp elimination of 5-nitro-benzisoxazole forming 2-cyano-4-nitrophenol has long served as a design platform of enzymes with non-natural reactions, providing new mechanistic ...

Researchers from The University of Osaka created a reagent for important building-block molecules with an abundant main-group element, gallium. These early findings show that an organic gallium ...

The kinetics of some chemical reactions has been extensively studied with ensemble-averaged methods 1,2. As for the molecular reaction dynamics, only some simple (few atoms) gas-phase elementary ...